The second website I would suggest you do something more like this -
Create a Website Using Adobe Dreamweaver | Web Design Tutorials | Creating a Website | Learn Adobe Flash, Photoshop and Dreamweaver - Very good for SEO that design is.
Also I wouldn't put the website name in the page title because you will already rank number 1 for that.
The first design is real simple and could work, I would recommend a welcome paragraph for SEO reasons.